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Ores, when smelted, also release gases, including X, or pollutant, gas. The exception is copper, which burns clean with no off-gassing.
There is a little thread about that that might be intresting. To sum it up, I really recommend placing your Furnace into a sealed room and pump out any gases and send it to a multi-filter facility for storage. You gonna need it later, especially N2, CO2 and H2O, but just add O2 as well and you are golden. Polluants/X as well if you want to use it for Jetpack (not indoors).
http://steamcommunity.com/app/544550/discussions/0/1621724915799080358/
EDIT: How do you correctly link a steam-owned discussion link?
however manually putting oxide and volatile in the furnace work like magic
EDIT: I tried to automate the Furnace ... it's not worth it. Stick to the manual oxide/volatile for the moment it works best. I would however build a valve and waste pipe ... so that you don't loose the CO2 for plants and possibly N2 and maybe some remains of O2/H2.
yeah I have a valve on the output already.
on the input line, do you mean to add another valve after the mixer ?
EDIT: And the temperature seems to increase exponential with the fuel pressure. Thats why continuous fueling is not a good idea. It burns it up in small intervalls instead of one big burn.