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Where the alloy recipe can boost output for sacrificing copper, which although not rare could be better spent on other things.
The copper alloy recipe is much more useful as Turing iron into copper is a much better trade.
Also if you find the recipe for iron wire grab it. This will allow you to make any copper product that requires cable or wire and save any copper nodes for the production of copper sheets, which you'll need allot of.
If you're still at a stage where re-arranging might be fairly common, or you're not exactly pressed for iron or copper, then Iron Alloy is perfectly serviceable, but heading into tier 7-8 you'll want to start making the switch to Pure Iron.
I'd say try and plan an area for your Pure Iron even if you're not aiming to build it right now, and bear it in mind for further expansion. You will eventually want to transition into it completely.
Pure copper, on the other hand, is essential. 240:600
Pure caterium never seemed worth the resources to build for the advantage, even though many of the nodes are near water.
In a pinch, do what you need to do.
If you have the space and time, Pure Ingots are boss. I absolutely LOVE looking out over 100-something Refineries spitting out thousands of Ingots, Sheets, Crystals, & Concrete. I find it absolutely satisfactory. ;)
You don't even have to wait for either.
480 Compacted Coal generates about 5GW power inside 67 Coal Generators.
Alas, I do not yet have that recipe. Been waiting for that for a while still. Hasn't come up as an option during research.