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https://oxygennotincluded.wiki.gg/wiki/Deodorizer
The Deodorizer is, as stated above, the solution for Polluted Oxygen. And since early Polluted Oxygen mostly comes from off-gassing Polluted Dirt/Water, plus the Swamp biome, a little bit of thought in placing Deodorizers (e.g. at the exit from your Latrine, since the Outhouse/Wash Basin produce Polluted Dirt/Water respectively) can generally get it all cleaned before it gets out of the contained areas where it's produced.
But the Deodorizer actually does nothing at all for Carbon Dioxide.
The Carbon Skimmer is the (earliest practical) way to remove (as much as your Dupes breathe out) Carbon Dioxide. You can also dig big enough pits below your base (which you place so your Dupes never have to enter them) that the CO2 settles there, instead of skimming it. This is overall the superior technique, but the Skimmer is very easy to implement once you have a plumbed Washroom, so remains a good choice for the less-experienced.
And do NOT use Gas Pumps early on (or Gas Filters once you have access to Refined Metal), except to fill Oxygen Masks if you choose to use them. (YMMV, but I personally think they're good in the early game.) If an area of your base is getting low on oxygen, build an Oxygen Diffuser there. Actively pumping it around takes too much power until you're at Electrolyzers. Then you can power the pumps from the byproduct Hydrogen, commonly called a SPOM.
And I can't dig out space fast enough to keep up with it. :(
Are there any options in the early game to lower that pressure?
This need to spread them out, coupled with the fact that each can nominally support 5 dupes, means that they pretty much inevitably spend most of their time stopped for max pressure. Which would be bad if they still consumed algae and power in that state... but they don't.
Dig lower to create more space and use ventilation to disperse the oxygen to further places until you can get a carbon scrubber going at the bottom where CO2 is collecting
Thanks. I also spent some time watching the gas overlay and realized the migration from the cavern was probably due to the polluted O2 being pushed out by CO2 build-up. Pretty neat!