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Over time, you'll be expanding in all directions. Just keep on creating a new pit for the junk gasses as needed. You can use a carbon scrubber(once it's available) at the bottom to intermittently reduce the buildup, if needed. Just add a power switch so it's not turning on and off needlessly for little bits.
Alternately, if you end up using a lot of coal power, it's typically a good idea to seal off that chamber and keep it's waste Co2 inside, along with a carbon scrubber. You can pump excess Co2 into there so that you have a single unified Co2 solution.
Arbor trees have an industrial line that produces catastrophic amounts of CO2. Even carbon skimmers can struggle with it. If the slickster ranches aren't up to speed, dunk the waste gas directly into space.
https://steamcommunity.com/sharedfiles/filedetails/?id=3167373576
2. Ferns turn CO2 into O2 but are temperature sensitive (requires dirt and water):
https://steamcommunity.com/sharedfiles/filedetails/?id=3167374908
https://steamcommunity.com/sharedfiles/filedetails/?id=3167375038
3. Destroy CO2 by means of the scrubber (requires sand and a bit of water, research needed):
https://steamcommunity.com/sharedfiles/filedetails/?id=3167373762
https://steamcommunity.com/sharedfiles/filedetails/?id=3167373868
Hope it helps you out
Or, if the co2 is at a good temperature, feed it through a heat exchanger first before destroying it.
If you already have Automation and the refined metal to build it circuits, I have screenshots of the devices I use in my profile.
As previously stated, dig holes down for the CO2 to pool in until you have other means of dealing with it.
Second, research the Carbon Skimmer. It's very easy research and only requires plumbing. It's a good idea to get the Water Sieve too. A single Carbon Skimmer will likely eliminate all your Co2 problems, but adding more is cheap if needed.
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From Wiki...
Since the Carbon Skimmer outputs exactly the same volume of liquid as it takes in, it can be built in a closed loop with a Water Sieve. This saves 240 W of power to run a Liquid Pump once the loop is given an initial quantity of water to work with.
One Sieve can serve up to 5 Skimmers.
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So in other words, once you get the flow going from the Skimmer to the Sieve and back, it will continuously loop and you don't need a pump, nor any sort of overflow management. It's a closed loop that requires no further attention.