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To test conductivity of pipes you could build a one segment of the pipe in a hot liquid, continue to preheat both the liquid and pipe to same temperature and then let a one packet of other liquid go through that pipe and check how much rises temperature of the packet inside pipe after it pass the hot section. This can give you idea how much heat per second materials can transfer.
Usually.
Heat capacity matters a bit if you want a liiitle biiit of stabalization, such as with Liquid Hydrogen production, where it can maybe help to avoid accidentally freezing all your hydrogen.
But generally, wolframite or aluminum is the way to go for things requiring absolutely maximal heat transfer in a small area; of course, if you have a LARGE cooling system, then even plain stone pipes or whatever metal you have volcanoes for will do just fine.
For insulated, I forget which common rock has the lowest transfer rate. Ceramic is the best mid game material, however, and of course Insulation itself is the best late game material for low transfer rate.
Because Gas pipes carry 1Kg while being bigger diameter and Liquid pipes carry 10 times more in smaller, but much denser pipes. 10 times difference in pressure and moving liquid instead of gases.
That is just my 2 pences.