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CO2 is horrible for cooling. Holds little to no heat in it so liquid CO2 will just vaporize long before it can cool anything else. Having CO2 gas around equipment can even lead to them overheating from CO2 being so poor at pulling heat away.
I built a freezer around a CO2 geyser and it can't even keep that cold without something else helping. CO2 is a waste product and isn't really worth keeping as anything you can do with CO2 is done MUCH better with something else.
Maybe keep 1 tank of it for some minor needs and just vent the rest of it into space.
Edit:
True
I mainly thought about irrigation, when writing that. (Despite offgassing pwater being my go to oxygen production method)
And you can uh at least let it absorb some heat and then delete it via venting into space or door crusher , even if it is the worst coolant it still can take some heat.
Slickers basically just give you meat, since the mass of oil/petroleum you get is not usable for anything. Making polluted water can be pretty useful for ceramics as pointed out and you can never really have enough of those, but if you don't want to use any of that, then the 2-3 set spawns of CO2 geysers on the nuclear planet that are specifically there to calm the beetas and produce rads in their biome are a waste yes. You will have those in every game though, since they are set spawns in their biome.
or polluted water -> steam + dirt -> clay -> ceramic.