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https://oxygennotincluded.fandom.com/wiki/Guide/Liquid_Airlock
If getting your dupes wet is a concern, and you have the resources, I've also seen folks set up one or two exo suit docks next to these to prevent wet dupes. (If the liquid lock is at your base exit, I put up as many docks as I have dupes, so everyone leaves in a suit).
https://forums.kleientertainment.com/forums/topic/111471-oniversity-hydrodynamics-how-to-create-a-single-liquid-waterfall/
Use ladders or mesh tiles as the floor on both sides of the waterfall, and no floor directly inside the waterfall itself, so that dupes "jump" through the falls. No debuffs. And you can make the falls as tall as you like.
Takes up some space above and below the falls, and uses a small amount of electricity to pump the water (but a liquid valve keeps the cost low).
Do note that this is not entirely self-sustaining (you need the pump) and so it could eventually fail if you stop supplying power (though this would take a while, due to liquid built up in the pipe behind the valve).
It is not something a new player is going to be able to implement successfully.
For starters, it's going to be huge when the most naively designed liquid lock only takes up 5x4 tiles of space.
It is going to be incredibly slow because vacuuming out a huge room will take forever.
Automating everything will be a nightmare - you can't lock the doors (because locked doors will force dupes to find a different route, and thus break the airlock), you have to account for various problems (What if two dupes try to use the airlock at the same time? What if a dupe tries to use the airlock and then changes his mind?), etc.
If the doors open one at a time the gas trapped in the chamber should just rest ontop of each other and not move out of the room.
You could just remove the doors and do it with a vertical shaft and ladder too if the pressure and density does not change much.
Have the main oxygen main base at the bottem and the hydrogen at the top.
This only works if you are preserving the "natural" vertical ordering of the gases, and only if the pressure stays relatively constant (on both sides).
I don't think adding doors will make maintain the boundary under any circumstances where it wouldn't be maintained without them, although an extra airtight door can be a handy backup measure on ANY threshold to limit the damage if something goes wrong (e.g. if your liquid somehow boils or freezes).