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Whatever is within the pipe will exchange heat with the pipe itself. So if you have built it from a bad material like Sedimentary Rock (because it is heat reactive) the steam will be chilled by the pipe itself and turn into water.
you'll want to use ingeous rock or ceramic for these insulated pipes. Ceramic is overall better but requires production, igneous is a quick and dirty insulative material that makes it great for insulated pipes.
second, gas pipes can be tough to transfer gasses that are close to a state change within i do a couple things to mitigate this wherever possible.
1. run the pipes through insulated walls
2. heat the material to a higher heat if possible before transferring it. this may require you to use a steel gas pump instead of a gold amalgum.
3. if possible run the pipe through warm areas along the way. it'll pre-heat the pipe so there will be less exchange of the materials transferring and the many pipe sections.
I think so, since there is no atmosphere around to have a temperature interaction. At least, that's what I imagine is happening there.