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Regarding electrolyzer overpressure - it follows general rule, like many other buildings, of 1800g max pressure.
If the sensor is close to the pump it won't be very much different.
There are plenty good electrolyzer setups out there.
https://steamcommunity.com/sharedfiles/filedetails/?id=1940594080
It takes time that the pressure in the pump area becomes close to the sensor area. The pressure in these two areas could be very different.
It has automation because you may have some use for a non-standard behavior with it.
If the sensor is right next to the pump then it won't be very far off from what the pump is. Yes, there will be some difference, but does it matter? And if it does matter, then you can adjust the sensor settings until the stabilization point over the pump reaches your ideal settings.
https://steamcommunity.com/sharedfiles/filedetails/?id=2112409888
https://steamcommunity.com/sharedfiles/filedetails/?id=2112409831
I like it, one less gas pump than the usual config we see for that and without the atmo sensors to regulate the pumps to sort the gases.
How's the output? I'm thinking this setup grabs 500g of gas more frequently and consistently and that this means it's producing more output due to electolyzers pausing less. How close does it get to supporting the theoretical 17.76 Dupes that a 2-electrolyzer setup can support (on paper)?