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You can try a heat exchange setup instead with a liquid that you are heating and keeping in pipes, flowing against the rail. That way you can have a greater temperature gradient. That room may be too uniform in its heat.
I don't think the material of the rail itself matters much, if anything, but don't quote me on that.
But if you just want to melt ice instantly then your best option is to build tempshift plates made out of it. You will lose a bit of cooling power this way but looks like you need something opposite here so you will spend a little less power to heat up the plates.
It won't work for CO2 though and won't be automatic.
Another solution would be to make metal block or diamond window spokes connected to the central box that the conveyors move through.
Also, use aluminum rather than copper if you have it. It's almost as good as thermium for conducting heat.
Here's the current version: https://i.imgur.com/iY1CVqk.jpg
Piping: https://i.imgur.com/u2QcqXN.jpg
Belts: https://i.imgur.com/tVXKNMl.jpg (when its mostly empty it looks like this: https://i.imgur.com/6Lo2U9K.jpg)
It is now capable of melting several tons of ice / CO2 per cycle and outputs at least 5kg/s of polluted water :) Thx guys!