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Now, the toilets create water and so you have to drain the excess... I think each flush turns like 5kg of water into 12kg polluted water, so you have to have a system to drain the excess. Showers and skimmers don't do that. You will have to run sand to them though.
Took me some time to figure this out as well.
As for OP, yes, it's very much so possible. But generally it's a better idea to use the Water Sieve to cool down really hot polluted water. As it always puts out 40°C water.
I'm not entirely certain if the Carbon Skimmer does the same thing.
And as pointed out by andrew, it's more useful to use it for fertilizer synthesizers. Which gives gas and fertilizer, for natural gas generators (also gives ph20 and carbon), and to feed fertilizer to sage hatches for coal. Which in turn is used in coal generators again, which spew out CO² which you can use for the Carbon Skimmer again.