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That being said, it doesn't really matter where you put your diffusers, because what you should do to ensure good oxygen circulation is use gas pipes/vents to pipe the gas from the diffusers to areas where your dupes are working. So if you choose to build them at the top, you'll pipe some gas to areas down below where dupes are working, and if you choose to build them at the bottom you'll be piping some gas to the top.
You cannot hope to just build them at the bottom and hope it all rises to the top because diffusers will reach maximum oxygen pressure within the small radius around it; you will have to pipe some away to areas with lower pressure or you will not be using the full potential output of a diffuser.
Pipes are cheap and don't cost power so it's a really good idea to pipe oxygen to different areas of the base (but keep your diffusers together/organized).
Then I make sure theres a few ditches towards the bottom, beneath the diffusers for all the co2 to collect.
Placement 'sort of' matters, though oxygen will slowly, eventually make its way to wherever its needed.
Also, don't forget deodorizers. They're super cheap, and you usually have more sand for them than you'll ever need anyway.
Slap those things anywhere you see slime or polluted water, and they'll turn polluted air into clean oxygen (sort of)
that said if the pressure is enough it will get pushed down, best location is in mid height of the base, it fills top first then spread to bottom.
and dont build to much of em.
i just take 4 dupes and 8 suits with one ox diffuser.
make a room for it, put the diffuser near the entry, place a pump 5 tiles away from the diffuser, put an air pressure sensor 2 tiles from the difuser between pump and diff. set it to 800.
now you can easily supply 4 dupes and 8 suits.
Different gases rise or sink depending on pressure and which other gases are around. Hydrogen is lighter than O2 and CO2 and chlorine are heavier.
Ideally, you should have enough airflow that gases can diffuse around the base on their own. I normally have a central shaft consisting of (ladder - mesh tile - fire pole). Diffusers sit on some of the mesh tiles. To the extent that placement matters, CO2 produced by dupes will flow downward, so there may be a slight benefit to putting oxygen production toward the top so that oxygen is following the CO2 flow rather than against it. Once you start using exosuits, you'll need pumps and pipes to supply oxygen to the docks. Once you switch to electrolysers, you'll want pumps and filters to separate the hydrogen (for cooling loops, rocketry, power, drecko ranching, or whatever).
So diffusers, I try to keep near critical buildings such as dinner and especially sleeping.
Because it all displaces, I prefer to try and keep it in the areas critical. If you let it bubble, it can "splash" The gases around keeping masses matched. Remember, two different elements cannot occupy same space. If you bubble, a small mass of gas/liquid will displace a large mass as it bubbles. This is a big issue with the oxyferns. Place oxyfern on level you want to be bottom of of O2 so it doesnt bubble the CO2 as bad.
So think in layers. Use bowls, caps and pits to layer out. Keep stuff where you want it. Hydrogen layers, oxygen layer, chlorine layer, etc. Stuff that outputs, always have it output to that layer area. Later use sensors and pumps to control and clear the contamination.
It's less likely to be blocked by high air pressure, that way.
Like I said a single manual door works just fine.This isn't about aesthetics.