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Other than that you have 2 options - use radiant pipes out of material with minimal SHC in vacuum, this will provide perfect insulation once pipes reach desired temperature. Or use ceramic (may use igneous too, but it is significantly worse) insulated pipes and loop them back into storage tank for re-cooling. If you leave hydrogen/oxygen sitting in anything other than insulated "insulation" pipe or cold enough pipe in vacuum it will break.
Also yes, Insulation is massively overexpensive to manufacture. This has been commented on a lot in the past. Ceramic is good enough of an insulator for the overwhelming majority of your situations that need better than igneous.
For insulation I don't use it much. Pipes is among the most useful uses for it though since tiles you can just double up and get as good as perfect insulation, or use vacuum seals. The only exception is for things like the steam turbine. Those tiles may be changed to insulation.
So normal pipe made out of Insulation can have quite high heat transfers if contents conductivity is high.
Where I use insulated pipes first is in my sour gas boiler. I like to do boil the oil with an aquatuner instead of using free power from a volcano in some random location, and that's a case where the temperature difference is large.
But even if it does not boil it still leaks some heat, resulting in some efficiency loss. Not huge, but why not remove it when possible?
Also yes, oil boiler is good place to use i too. I prefer to build whole thing in vacuum to avoid needing too much (still non-ideal) ceramics, but for coolant pipes inside sour gas insulation is very good (but still not critical, similarly to steam/water loops).
If you have 3 different ones do you have it because you need 3 different temperatures? If not you can put them in series and avoid the risk your describe.
Not that it bothered me that much, the place was designed to be accessible by dupes from the start so they just go in and fix the pipe once in some very large time. And few insulated insulation pipes fixed that issue now.
Switching that loop to supercoolant is something that i might do at some point, but i do not even want to know how much coolant it contains, probably something like ~20T. Not looking forward to producing that much supercoolant just to save some power.
Also i tend to leave a lot of early-mid game contraptions built out of "primitive" materials as is apart from small and easy changes like those pipes, because power is nearly unlimited late game anyway, saving something like ~500-1000w might be fun if efficiency is the main goal, but is totally unimportant otherwise.
You can get very close(99% efficiency) but it won't be power positive. So you can't create infinite energy because it will be game balance issue.