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Some numbers for anyone having same problem:
Reduced steam pressure down to 70 Kg Could not say exactly when volcano stopped being over pressure, maybe has to be less than 100 Kg ?
As for whether a turbine needs a minimum amount of steam, I don't know but I had two volcanoes with the same problem and reduced the steam in one to 50 Kg and turbine still functions fine.
By the way, does anyone know if there is way to calculate how much water per tile to put in initially, in order to end up with say 50 Kg of steam per tile when it boils?
Please don't tell me it is 50 Kg I will feel stupid XD
So I was putting far too much water in to start with, I will bear that in mind when building the set up in future. I was trying to minimise the amount of gas in the room to start with, that is why I put so much water in.
Don't really want to have to pump all gas out first, then I would have to either leave the pump in the room after and it becomes over heated, or if I dismantle it, then the dupes will expel CO2 while doing it and I am back to having other gas mixed in with steam again.