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Chlorine is the bee in my bonnet. Even the tiniest bit sneaks in and it gravitates to my farms like a magnet. Then it just drifts around stopping plant growth and never going away. Trying to pump it out is a horror because there is no good place to send it. Running pipes to a chlorine area just means the idiot dupes will let more in. The only good solutions I've found:
1) Find one of those big chasms that is mostly H2. Vent it to the top of that and it will drift down and the H2 will keep it there.
2) (Hypothetical - I haven't actually tried this, but it should work) Build a box. Build the exhaust vent into it ahead of time so you don't ever need to open it. Pump all the air out. Then just fill it with chlorine. I doubt you will ever have pressure problems, but if you do just see 3.
3) Some people have had good luck with liqifying it. That takes some skill and access to the right stuff. It's also a big investment unless you have some use for the liquid chlorine. Perhaps as a coolant fluid. Or a gift for someone you don't like.
Needless to say: Build many airlocks if you have to go through chlorine. As many as you can stand but make them MECHANICAL airlocks. You know how dupes are: Go through five manual airlocks, needs to pee so goes back through five manual airlocks. Pees and goes out through five manual airlocks, decides it's a mite peckish so goes back through five manual airlocks. Eats and goes out through five manual airlocks, decides the microbe mushers needs 50kg of water so goes back through five manual airlocks. Goes out through five manual airlocks and...cycle over, nap time. You stare at the screen while they sleep. Then lock all the airlocks and pump all the air out of the base. It's a mercy, really.
Mechanical airlocks prevent euthanasia. Remember.
Chlorine is also the required atmosphere to sustain the growth of Balm Lilies -- they will accept nothing else. Balm Lilies are also kind of important to working in the Slime, via Vita Chews for the boost to Immunity.
That being said, you are correct, collecting and storing Chlorine is a pain.