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looks like you have some sort of file permission issue. First of all, don't run Wallpaper Engine or Steam as administrator, it can cause file permission and other problems.
The second error is actually a Unity error coming from the Wallpaper you are trying to use directly, I assume that it was not properly downloaded, is corrupted or there is yet another file permissions problem.
My suggestion would be to turn off Wallpaper Engine (also check the task manager processes), turn of Steam and then delete your workshop directory, which, in your case, is at E:/SteamLibrary/steamapps/workshop. Afterwards also delete your wallpaper_engine directory which is likely in Steam\SteamApps\common\wallpaper_engine when starting in your Steam directory.
Try starting Steam normally and re-install again. If this is not working you may have an anti-virus or something like that blocking Steam from writing Workshop files, for example.