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The kicker is, to do the Alphys hangout you have to receive a call from Undyne on the bridge between MTT Resort and the Core. That call will only become available after you've defeated Photoshop Flowey and backtrack, on top of also completing the hangouts for Papyrus and Undyne.
Defeating Flowey however does carry over into subsequent runs, where he'll refuse to fight you again until you either complete a pacifist or genocide run. This means the call from Undyne becomes available after Mettaton EX is defeated and Alphys runs of to her lab. This means you don't have to go through the New Home sequence and fight Asgore on your second run.
After the hangout with Alphys, you'll be guided to return to her lab where you'll find a note and the way into the True Lab will be open. Once you enter the True Lab you are locked into getting the Pacifist Ending.
Will this playthrough be any different? Maybe I'll just YouTube it. Don't think I can be bothered doing it all again.
The pacifist ending exclusive content is definitely worth another run through. I mean, Undertale is a very short game for this very reason.
Eh I already my last playthrough as a pacifist. I just didn't do a couple steps apparently. Can't be bothered doing it again just to do those couple things. It's not a long game but I definitely don't feel like doing it all again. Thanks for the reply!
After his fight befriend him.
Go back to his house.
Go to his room.
Date him.
Then it comes to Undyne...
The reason you didn't get the option to hang out with Undyne is because you needed to pour water on Undyne's head, you do this by:
Go to the water fountain (not a fountain but like the things you get in work offices).
Interact with it (A Xbox or Switch/ENTER Computer/Steam).
Get some water.
Go to Undyne.
Interact with her (A Xbox or Switch/ENTER Computer/Steam).
Pour it on her head.
Then you will continue True Pacifist.
For more info got to the Undertale Wiki!