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But if you must move it, just do it. Only problem is that if you ever verify the install, steam will download it again, leaving duplicate files in your system.
Either leave them there, or move them to wherever you want then uncheck the DLC referring to the soundtrack on steam (Which will "uninstall" it, making sure steam won't download it again).
And in case you still haven't figured, the music files are under the game install directory.