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Edit: Disregard - this is the RE recipe. Apologies for confusion.
Are you playing the standard Survival game on Akua? IF so there are dozens of Carbon surface rocks laying around everywhere. use your Survival tool to harvest them.
https://steamcommunity.com/sharedfiles/filedetails/?id=2932788834
That is a Carbon surface rock. There are also underground Carbon deposits.
But you could never make Carbon Substrate in the Emergency constructor.
I also reverted the recipe for it myself, as well as reverting the recipes for the portables to require iron ore again.
Fired up the wrong creative mode to check before posting - I was in RE creative instead of vanilla (which I never play anymore). It happens. However next time before being snarky you could simply check a profile to see how much time a person's put into a game recently. In my case it's around 110 hours the last two weeks.
Carbon deposits are reasonably common throughout the galaxy. Converting the extra stone you mine along with other ores will also be a reliable source.
On the starting moons, there's even more of it, especially on the surface. There should be black rocks of carbon all around you as you land. Snag a few, pick some flowers for tech points, same old story, same old song and dance.
This.
"it just refused to create it."
What refused to create what?
I think I know what you are trying to do, but I am not 100% sure. If you were more explicit it would help. Tell us exactly what you are trying to make and exactly how you are trying to do it.
I guess that's what OP was talking about without mentioning PE which would have helped us more to not make confusing answers. This problem simply doesn't exist in vanilla, be it the new start 1.8+ or before, and in In RE you would need only 5 iron ores to build a constructor, so that cannot be OP's problem.
In the PE default start, if you explore you'll soon find at least a motorbike which will speed up things for you to explore other planet regions and find carbon. The motorbike could be random though, and if that's the case then a PE start will be pretty nasty without constructor.
But this is just a prelude for how more grinding is involved in RE/PE.