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"Primary/Secondary in game lists only a single resource for most planets, and Atrox has none, so it really is pointless to list things as such on the wiki. I would like a more accurate listing of where on each planet a resource can be found. In my testing, in-game the primary resources are underground, while secondary is on the surface typically, with chances of appearing deeper in the planet."
https://astroneer.gamepedia.com/User_talk:Bbp9857
You can also find lithium on the surface of Novus, in the most rugged mountainous biome. If you have a buggy, its not to hard to get around on that planet. I even take mine down into the caves.