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The Gremist in Skellige will most likely be able to sell you formulas that you don't have by the time you get around to meeting him, but that's generally mid game (the quest you need to do for him to unlock the ability to shop from him is recommended level 24 if I remember correctly).
Are you 100% sure? On my current playthough I went an unusually long time without finding the basic Blizzard recipe and I think I bought all 3 formulations of it from Gremist (basic, enhanced, and superior). I could be misremembering who I bought those from though, but I'm fairly sure it was him.
I think he just sells the majority of the stuff you are missing.
Here