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But if you want to use the stand alone client you will need to email support support@grindinggear.com
They will ask you some security questions and ask for an email address to link to the account, from there you can set a password and then it's just a case of downloading the standalone client and logging in.
FYI you can use both after that, if there is something that you need on steam (like access to your steam wallet for mtx)
And support usualy has someone on over the weekend but most of them are off, it's not a major problem and they are usualy quite quick to get to you.