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more information here: https://pathofexile.gamepedia.com/Item_socket
See... You say that - but here are several items with a search hard cap of ilvl 45 that have 6s (not sure if link will work):
https://www.pathofexile.com/trade/search/Hardcore%20Incursion/0nK2npFg
EDIT: Thinking about it, this may be a situation of "Items from strongboxes with of Complexity affix" over riding the hard limit. So, while its possible, it may not be possible on a "typical" item.
After that you are free to try and 6 link it since only the number of sockets is based on item level.
However RandomHero gave you the reason why some items have 6 sockets below ilvl 50.
I used to did ALOT of low lvl pvp back when they had rewards / leaderboards for it, and I ran with 6 socket rare staff / chest all blow ilvl of 50 if I remember correctly.
On the bright side this is most likely no concern of yours as you wont spend 100+ ex on low lvl pvp gear :)
tabulas, loreweave and oni-goroshis always have 6 sockets