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However, as stated above, some DoT applications are based on the damage of a hit, and if that hit crits and does more daamge, that DoT would tick for more damage.
Skills that have inherent dots never crit, like essence drain, righteous fire, scorching ray, caustic arrow vortex etc.
You can also play a RF totem chieftain. Chieftain ascendancy has a node that makes totems immune to fire, so the RF doesn't damage the totem casting it, you just pop a stick and melt everything around.
All spells have crit chance listed. If there is no crit chance listed, it cannot crit ever.
RF is a degen not a DoT
Not entirely true! for instance with the crit shrine some spell do get crit like incinerate
Other interactions with RF is that elemental damage does scale the dmg that RF deals but it will not scale the dmg of a burn from another spell. Example - you cast fireball and it crits/ignites the enemy, the damage of the burn only takes into account the dmg of the actual spell that applied it, the only way to further scale the dmg of the burn is to link the gem with increased burning or take burning damage passives or to take damage over time nodes off the tree or to reduce the enemies resistances.
Also to the person saying that spells w/o crit chance cannot crit is wrong - you can link the skill with increased critical strikes gem to add crit to the spell and you can use the Assassin ascendancy traits to give the spell a crit chance and Diamond Shrines will give you 100% crit with spells that hit and as long as you don't have Resolute Technique.
To the user asking why people take ele overload with it - they're using cyclone or some other kind of skill to trigger it - usually orb of storms + inc aoe + inc crit strikes. Drop that and you can trigger EO easily.