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Willlpower increases the rest aoff the dmg types and duration dmg
You can test it yourself if you put a point (or use gear/item) in spirit, you'll see the damage increase on both acid and poison abilities.
There's signs in the devotion constellation that can help with that.
There's some like Affliction, Manticore and Abomination that would probably work well for what you have in mind. They grant bonus damage% for poison/acid as you work towards the ability at the end of those signs. There's probably others too, but that is just an example.
Most of the acid/poison stuff is in the south east section of the devotion constellation if I rememeber correctly. There's probably a few up in the north east section too.
You could also try abilities granted by components such as Poison Bomb (Mutagenic Ichor), which I imagine would be very effective with that build.
You'll also find gear later on that will further boost your poison/acid%. For example: Alchemist Belt (edit: epic tier item), which increases your acid damage by 24%.
Goodluck.
You're welcome, may the cruel and fickle gods of RNG see fit to grant you some poison/acid gear.
Best of luck in your endeavours.