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other stuff can be unlocked during levelling with certain MIs https://www.grimtools.com/db/search?query=%22chaos%20damage%20to%22%20%22rare%22%20%22level%3A%2094%22&in_description=1&exact_match=0 (exists in various lower level version too, just using 94 to get rid of duplicates)
You can build around skills that do native Chaos damage, for example Sigil or Doom bolt. Or you can pick something that's easy to convert to chaos damage, by some easily accessible MI. Or you can do both at once. Usually, you won't get full damage conversion during leveling anyway.
This is obviously not possible for all builds, and sometimes you need to go different way, what already worked for me on multiple characters, was leveling with fire, as items allowed slowly converting to fire/chaos, chaos/fire and if possible purely chaos. This approach works well, because you can use same/similar devotion setup for both damage types. Nice example of this can be Chaos Fire Strike builds, there was a thread about that recently.
But this might not be always possible or viable, depending on build, so you might also end up leveling with completely different setup and switching everything later.
EDIT: Thread I mentioned, not exactly the same topic, but it can serve as an inspiration: https://steamcommunity.com/app/219990/discussions/0/4357869680025049241/
you don't even need the darkblaze set
look for a medal wich convert firetrike into chaos damage (sigil of chton)
Edit: Link the Crate Forum post on the build: https://forums.crateentertainment.com/t/1-1-9-8-1-2-0-3-darkness-palpable-s-b-chaos-rf-sentinel-sr-vid/132111
Link to Grimtools:
https://www.grimtools.com/calc/YVWdXGnZ