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Deceiver acid gunslinger, this is just the main item idea
EDIT: this is something I can thinks off https://www.grimtools.com/calc/DV97wPPN
I have a pure lightning based vindicator gunslinger that can easily solo SR up to like 70. Its not like some uber build that gonna change the world or anything but it can easily handle most of the games content sans the stupid celestial uber bosses.
As for chaos the dark source set is still the best I believe, vitality and poison based pistol builds lack good support gear wise. By that I mean they can work (most things can) but your always better off going dw melee if your doing poison or acid its just better in every way.
gun/xbow acid or vit damage mostly are caster stuff while chaos have many option but have limited resist reduction.
Purifier have two chaos resist reduction but the class itself lack or minimal chaos damage support. Occultist have tons of chaos damage but lack support, but the Harbinger set support ranged chaos occultist, not to mention it can be combined with rah'zin set.
The different is which one that support your playstyle. For example if i'm playing as an auto attacker deceiver like I send you above, I'll be crafting and using shard of beronath as main damage and pick all the inquisitor wps skill while my gear and devotion will be more about attack speed and adcth, that's why for said build I pick Venomlance (https://www.grimtools.com/db/items/8755) instead of Mythical Quillthrower of Dreeg (https://www.grimtools.com/db/items/9399). If I'm playing caster I might be using the Dreeg one and not crafting shard of beronath, not learning any of the inquisition wps and maxing the skill dreeg evil eye while the gear and devo are focused on cast speed
Rahzin/Harbinger Witchblade is also excellent for chaos.
Like Rodhull said, poison, acid and vitality are not really set up for ranged and are optimized for DW melee instead.
https://www.grimtools.com/calc/4NOJv1YZ
It works fine, it's just the 'blade' throwing off intuitive notions of what the class is about or can do. The naming of the Nightblade mastery has the same problem.
Markovian and zolhan tech for extra ranged damage proc but zolhan aoe only work with melee, so I craft seal of the void for extra wps proc and it give aoe option with ranged weapon. Basic attack with cadence and its fighting form give aoe option for melee and pierce through enemy if using ranged.
At first I dont use CoF as it have no chaos resist reduction, but symbol of solael component have skill that reduce enemy chaos resist. If you want to play DW gunslinger I suggest use the symbol of solael component on off hand and seal of the void on main hand.
Also look at my devo path, it give you both Abomination and Dying God to greatly improve your chaos damage. Solael witchblade and Fiend also give a bit aoe damage while the former also reduce chaos resistance.
In the end, unlike the aoe damage from inquisitor storm spread, my aoe come from piercing multiple enemy. I also dont plan on using cadence for long and will remove it as soon as I complete Rah'zin set and Harbinger set, making the goal of the build into like this, and it stay as melee and ranged build:
https://www.grimtools.com/calc/8NKdy6n2