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To turn your weapon into a chaosblade, you need to upgrade it to +5, then modify it to a fire weapon at Vamos the skeleton blacksmit at the bottom of the Catacombs. Then you need to kill Ceaseless discharge and get the chaos ember guarded by a whole bunch of Taurus demons in Demon Ruins.
here's a handy chart. http://darksouls.wdfiles.com/local--files/upgrade/upgrade-chart.jpg
Use the wikis to find out where you find the required upgrade materials.
Are you talking about a chaos uchigatana or the chaos blade? You make the chaos blade with a +10 katana and soul of Quelaag at the giant blacksmith. A chaos Uchi would be through the fire/chaos path using the smith in the catacombs.
http://darksouls.wikidot.com/chaos-blade
Agreed, my first run, I just simply rolled over the lava, and probably got lucky... I did die after I picked it up, but - hey - YOLO!