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https://witcher.fandom.com/wiki/Vitality#In_The_Witcher_2:_Assassins_of_Kings
Looks like it's only couple of steel swords and the amulet which can be missed on in the early game.
You can farm harpies in the ravine/near Visionary's home - it is safer, but more tedious. Loot is nice, though.
It's just another potion recipe. I can't remember exactly which merchant I got it from, but it was definitely as early as Chapter 1. White Rafford's gives you like 50% more vitality, so if you pair it with Swallow, you'll start fights off with a nice hitpoint boost. Now, White Rafford's uses like 40-50 % toxicity, so you'll only be able to take like one other potion with it (Swallow), so I'd say only use it if you really think you're going to need it and be in a fight where you're going to take a ton of damage. I usually just something like Tawny Owl + Swallow + Rook. That's a good potion combo that gives you increased vigor & health regen + extra sword damage which is usually enough to take care of just about anything and you can always use Quen in a pinch to give yourself some time to regenerate health from Swallow.