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Providing you meet the other requirements like ram, graphics card etc.
The game is not meant to run on Windows XP and this is even mentioned in the spec requirements.
http://en.wikipedia.org/wiki/Assassin's_Creed_III#Development
http://www.eurogamer.net/articles/2012-09-26-assassins-creed-3-pc-system-requirements-chop-windows-xp-support
I guess not...
Edit: Ah, it is DX9, 10 and 11.
My bad.