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This is really confusing. If you are trying to open a model in Blender, why are you worried about the VTFs? If you have no VTF files, then you don't have a texture for the model.
VTX (VerTeX) files store information about the model's surface, stored in the /models folder (along with VVD - Valve Vertex Data - and MDL - MoDeL - files).
Basically, as EmperorFaiz says, you're looking in the wrong place.
Valve materials and textures are .vmt (Valve Material Text files) and .vtf (Valve Material Texture files.) The texture files have to be converted to an image format supported by Blender (png, tga, dds, jpg, etc) in order to paint your model with a them in Blender. Valve materials are found under the Materials folder in a mod folder.