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The Steam Deck is designed to work with any USB PD-compliant 45W+ charger, and they did that by using the 15V rail, at 3A.
I don't think it has any modes other than the 2 you've seen. It's not engineered for higher current than 3A. USB-PD doesn't normally use higher than 3A below 60W. (Maybe there are some extensions I'm unaware of, but the Steam Deck doesn't support them).
You won't have any luck with a non-USB-PD-compliant charger that doesn't have the 15V supply.
You can see actual charge rate in the desktop, in the Energy Monitor tool, acccessible via the battery icon on the taskbar. Peak charge rate is something like 20-22W for the LCD version, 30-34W for the OLED version.