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Then for your tier 2 tome you need to have two tier 1, for your first tier 3 two tier 2 etc. The first three tiers can be of any affinity, but tier 4 and 5 you need a certain amount of affinity to unlock, so if you're focused mainly on order, you will only have order tomes to choose from. Also I believe you can only choose one tier 5 tome, as opposed to tiers 1 to 4 where you can choose two.
Hope it helps! Cheers
EDIT: Also keep in mind there are specific techs depending on culture, and also general techs (like the magical crows for exploring), so maybe you also researched some of that and that's why you unlocked a third tome
For Tier 1-3 tomes, you can obtain them whenever you want. Even skipping their 1st and 2nd tiers entirely and going straight for 3.
However, in order to obtain a Tier 4 tome, you need a minimum of 6 ranks in its respective affinity. While to obtain a Tier 5 tome, you need a minimum of 8 ranks.