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You have to hit them multiple times. You can stun them for as long you have stamina too.
Test it yourself. When one is not stunned, press and hold Q and it shows the overall catch chance. Stun it, and hold Q again, its the same
This
Level 5 .... :)
You dont need anything to catch these buggers, it should not fail even when using a low level pike to hit them and the lowest pal spheres.
I think you have to test it on something a bit beefier :)
You get +30% of whatever your current capture chance is.
As others said these stun battons are helpful if you want to catch lower level pals if everything else you have will just instakill it and throwing a sphere without applying a status effect still has a very low chance of capture.