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Damn, I already killed Leda, I didn’t think it would break the quest
Meet Thiollier for the first time at the 'Pillar Path Cross' Site of Grace.
After Miquella's Great Rune has broken, speak to Thiollier again at Pillar Path Cross.
Speak to Moore at the 'Main Gate Cross' Site of Grace and receive the Black Syrup item.
Give the Black Syrup to Thiollier, and speak to him until he gives you Thiollier's Concoction in return and says he'll be moving to the Southern Shore to find St Trina.
Travel to the Cerulean Coast and find the entrance to the Stone Coffin Fissure dungeon.
Make your way to the end of Stone Coffin Fissure and defeat the Putrescent Knight.
Speak to Thiollier in the Garden of Deep Purple, next to St Trina.
Imbibe nectar four times from St Trina, then speak to Thiollier again to 'Pass on St Trina's words to him'.
When he refuses, select 'Try to pass on St Trina's words again', and either rest at the Site of Grace or imbibe nectar one more time from St Trina.
Defeat Thiollier in battle when he invades your world to fight you.
Speak to Thiollier once more and 'Pass on St Trina's words' to him now he's ready to listen, and exhaust his dialogue.
Continue through the game until you reach Enir-Ilim and the fight with Leda. Summon Thiollier to help you.
Summon Thiollier in the final boss battle.
After you've completed the final boss, rest at the Site of Grace and interact with Thioller's body to receive your reward items.
But he’s not at the first meeting place =c
It's actually kind of remarkable how Fromsoft has taken an already rough and easy-to-mess-up quest system and managed to made it worse.