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Sounds like CPU going over max temp, same symptoms. PCs usually just abruptly turn off when CPUs go over max temp. I'd first check CPU temps if I was your friend.
2nd thing I'd check GPU temps as well.
3rd thing that comes to mind is PSU. Same thing can happen if PSU is faulty, or just doesn't have enough power to deliver during stress.
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In any case, I highly advise limiting game fps if not done already. Either via in game settings or RivaTuner (or even Nvidia Control Panel). If he's playing uncapped, that easily might be the reason for overheating, especially since both 6600XT or any i5 gen 9 are far away from high end components nowdays.
Also, on what resolution is he playing and what's the refresh rate of his monitor?
can try leaving the side open with a fan on it to test if its overhearing if not can also get a program -not sure what one for amd- that can limit the power draw of the gpu that can help to with power draw