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T-65 for radiation / energy.
Union for poison.
Pick the PA you like the best aesthetically because the differences between them are negligible when it comes to damage that actually matters excluding Union because the poison resistance is actually very strong if you end up dealing with enemies that deal it.
At the end of the day, legendary PA with Overeaters will basically make all of them equal except for Excavator which is noticeably weaker than all of the rest.
If you seek immortality in PA, stacking Overeater Sentinel pieces along with damage reduction % perks will get you there.
- didnt read your question fully, stay with the Union.
Many still play with excavator and it protects them too for example.
It pretty much just comes down to which armor you like visually pretty much.
Below is my gameplay of Daily Ops Uplink and Decryption. I use T-65 for Uplink, and when I take a beating, I only get tickle damage or none at all, even when my health is super-low. But in Decryption, enemies ignore all my damage resistance, and I have to rely on the 12% damage reduction of Hellcat (plus the 42% damage reduction that all power armor types have):
https://www.youtube.com/watch?v=fqF87viyfOI
I try using hellcat, ultracite and excavator and is hard to notice a diference on damage taken. So i just use excavator with overeater+eletric absorpion+funky duds utill i get union. 100+ carryweight is really nice.