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In the forest, Gorge Junkyard has a hole of black titanium ore. A chemistry bench is inside the shed.
Running Earth Mover quest at the Mount Blair workshop yields plenty of different ores into a collection box for the duration of 30 minutes.
Buy the maps they sell (3 per server) and click on them in pipboy. They'll start the Lucky Strike quest.
Find the mound in the area. Click on it. Receive Black Titanium and other resources. All 3 maps yield around 60 Black Titanium.
Ultracite power armor is much better.
If you are making it for the carry weight set boost then I "guess" bother but your still easy pickings if you don't know the pvp rules.