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Keep visiting them and keep giving Nectar/Ambrosia to both. You need to build your relationship with both of them, not just one.
Same for all other acquaintances and members of the family. For example you cannot just build a relationship with Nyx in order to get Chaos to talk to her. You need to do it for both of them.
Also keep in mind that sometimes even if you max out a relationship, the dialogue to progress it won't immediately trigger the next time you talk to someone. So just keep going at it and you'll get them to talk eventually.