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I've been using Arbalest on them in Gambit all of yesterday, no luck, or is there another location I should be trying?
Barrier Champions are something completely different. They will be called something like 'Barrier Servitor', 'Barrier Colossus', etc; after taking some damage, they generate a shield around themselves, while they regenerate their health. Hitting this with anti-barrier weaponry (or effects) breaks the shield, stops the regen and stuns the champion, the shield is unbreakable otherwise.
You want to to look for them in Legend/Master Lost Sectors, in Nightfalls - any activity that includes Champions will say so in their modifiers.
Dares of Eternity will have barrier champs for wave 1 cabal, wave 2 cabal, and wave 3 hive iirc.
Arbalest will work, but as EckyThump said, you're looking in the wrong place for them.
My Solar Titan build for Lost sectors, I throw a hammer to trigger Radiant before they use their shield, rifle them until they shield and switch to my trace/machine gun to break the shield (as auto rifle already stuns Overload champions, it can't break a Barrier champion for some god forsaken reason).
Works like a charm.
Legend Lost Sectors is the best place to stun champions btw.