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To unlock it, you need to kill 500 enemies with direct hits and 1000 enemies with the aoe explosion. These can be killed anywhere, not just in strikes.
Step 1 - Play Strikes and Crucible until it drops for you. It is totally random and you can't do anything to increase the chances.
Step 2 - For Y1 catalysts, you insert them straight away (it will let it produce orbs of light even without completing the catalyst)
Step 3 - Now you've got to follow the catalyst's instructions. For Sunshot it is to kill 500 enemies directly, and 1,000 with the weapon's Sun Blast special effect.
Step 4 - When you've done this, it will say 'Masterwork Objective Complete', you re-apply the catalyst in the same way as Step 2, but this time it masterworks the exotic and adds the catalyst's stat boosts/special perks - in this case a range and stability increase.
Y2 and later catalysts don't get inserted at step 2. You just go straight onto working on meeting their objectives before you can insert it.
Any recommended spots now that whisper has gone?
Last wish raid, shuro chi encounter. There's a code you can input at the wall of wishes that takes you straight there. Start the encounter, kill a bunch of ♥♥♥♥, die and restart.
For me I just played without paying too much attention to the catalyst, and eventually it dropped.
It's a good catalyst but nothing amazing, so don't stress too much over it.