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I try to get it since 2 years in strikes.
My dad just got sunshot and its catalyst in the same week...
All catalysts are worth doing, if for nothing else but to be less bored. Some of them though, like Eriana's, Izanagi's, Acrius etc are giving major boost. Outbreak's cata is far from being bad, if you need wave clearing or boss damage in Leviathan or Last Wish, its wiping the battlefield.
The worst ones are likely Mida and Worldline. Mida gets something that it doesnt need and Worldline got pretty much pulverized by the nerf, barely anyone using it.
I don't bother much with catalyst hunting ( I do find some though ), but should you ideally have the weapon in your inventory if your hunting a specific catalyst ? Or will it just drop activity-wise ?
So far, for most of my exotic catalyst drops I didn't have the weapon in my inventory, so it's definitely not required. I don't know if it increases your chance, but I doubt it.
I got lucky " once " with a good roll and the catylyst. She's a beast !
Black Talon is frequently used in PvP because its ranged and you can peak with it.