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There are also other missions that will reward you with purple duty officers, like the Ghosts of the Jem'Hadar, Project Chrysalis, Consular Authority, Facility 4028, and Caitian Diaspora chains.
Using this page again, we can determine individual mission requirements:
https://docs.google.com/spreadsheet/ccc?key=0An0kX7PcNK-vdG1oNWl1ZGlsYzN0Z3NCRFJLWkJLa2c#gid=109
The chains Ghosts of the Jem'Hadar and Project Chrysalis are not repeatable, and you will only be rewarded with the unique purple doffs they give once.
Consular authority, Facility 4028, and Caitian Diaspora all give a repeatable final mission that can be done an infinite number of times in a similar vein to the the Colonization chains mentioned in the above post.
Facility 4028 has the most useful repeatable mission in Strike Against Fugitive Support Network. Upon getting a critical on this mission, you will receive contraband, a bunch of prisoners, and a blue Vorta that you can exchange in the Beta Ursae sector block mission 'Exchange Prisoners with Dominion' for a REALLY GOOD blue or purple duty officer. Some of these doffs can be worth anywhere from 500k to 100mil.
The final Caitian Diaspora mission, Caitian Field Flight Training Program, can give a purple Caitian duty officer. The catch-22 is that the best duty officers to have the highest rating to get these duty officers are in purple duty officers, so you may need to buy a few off the exchange to be able to chance getting more. Don't worry, as some of the purple duty officers this mission rewards can worth upwards of 20mil, and you will soon recoup your losses.
Consular authority will unlock a repeatable mission that will give you duty officers, but be noted that the 4th mission will permanently remove the duty officer you assign to complete from your roster, so use a common one.