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The link you did on your Xbox account only allows Xbox to pull some basic info from your Steam account.
It is a one way link, no info about your Xbox account is shared with Steam.
Steam itself dose offer a way to link 3rd party account to it and pull info from them. Which is what you would need to see your Xbox friends.
As far as I'm aware, It's not possible to add your Xbox friends to your Steam friends list UNLESS they also have a Steam account.