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As oobymach has said, the only advantage is its non-corrosive nature, but that doesn't really matter with today's alloys.
Audio quality is not really affected. The signal being passed is not being limited with any of the possible metals one could use, so a specific metal is rather pointless.
It can, however, help with aging. But hopefully you are not constantly exposing it to the elements. I wouldn't recommend keeping a pc outside lol
That's what is keeping me from building my dream pc. If I did that, I'd have to live in a cardboard box.
You will find high-end gaming motherboard do this, such as:
Asus ROG (Republic of Gamers)
Gigabyte G1 and Sniper series, etc
As for the connector end... Gold is actually a worse conductor of electricity than copper, though in practice that matters little. The only real, physical reason to use gold is that unlike copper, it doesn't tarnish. Over time copper oxidizes when exposed to air, gold doesn't have this issue. Nickel also oxidizes over time, here the level of your signal will fall down filled with scratches and noises over time causing interference. Depending on your air, this could take up to 15 years to become noticable.
Gold-plated connectors offer a benefit, but it's a marginal one at best and will take years to even be noticed. Soundwise there's no difference.
If you just want to build a game PC with 1 GPU and 1 or 2 hdd's any mobo will do.
Both are great...
You will find ROG offers more gaming features however, such as the audio and networking. You do pay for them however, but saves you from getting them separately.
Asus TUF Mark 1 will use Realtek ALC 8-Channel audio.
Asus ROG Strix Z270, for example, will use ROG SupremeFX 8-Channel audio. SupremeFX is Realtek, with additional shielding and features.
You would also get a gaming ethernet card and Wi-Fi 802.11 AC, Bluetooth, etc.
It just depends if you want/need those extras?
If not, the TUF offers durability in a more protected rugged design.
ps: As the others have already mentioned, performance wise, it won't matter (there's no bottlenecking for those), it's more to do with the features you are after and will make use of or not.