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This doesn't sound like Steam behaviour, unless perhaps you'd mapped Game Bar's screenshot shortcut to Share in a Steam controller layout or something?
Are you using the regular controller or an Elite etc?
https://www.reddit.com/r/pcgamingtechsupport/comments/1ah7ebr/capture_button_on_xbox_series_x_controller/
I solved this problem by downgrading Windows to build 22631.2861 and disabling the update.