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http://www.teachwithportals.com/index.php/faq/
http://forums.steampowered.com/forums/showthread.php?t=2797546
Also Steam for schools is not accepting new applications any more it seems according to that same blogpost.
if you think you can get around installing the games on every machine then i am afraid i have to say it is not possible.
if you however want to create a batch file to manage the account(s) itself/themselves.
this is how i would go about it:
1- login to each account on each pc using the steamguard code.
2- take the ssfn from each pc.
3- turn on family view / limit everything that u feel the accounts should not have access to.
4- create a batch file with all 18 steam accounts logins and have it copy all 18 ssfn files into the steam folder directory.
then if u do not trust ur students or whatever, i would turn that batchfile into an exe and encrypt it.
i could shown u in details if need be.