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They can however be shared via Steam Families, provided the game allows it.
You can read more about Steam families here
https://store.steampowered.com/news/app/593110/view/4149575031735702628
You could have her create an account of her own and then you could family share your library to her account, but you'd be in the same position of not being able to use the same library at the same time.
There is, however, an upcoming change to the family sharing that would allow multiple games from the same library to be played at the same time but it's still working its way through the Beta version of the client.
Not sure if any of that is a solution for you but those are the only options so far.