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Some things to try here (Ignore the Combo Cleaner ad):
https://blog.pcrisk.com/windows/13706-failed-to-load-steamui-dll
For malwares, go for Malwarebytes free version.
This issue is usually caused by third-party software that interfere with Steam.
Things like an anti-virus software, cleaners etc are all known culprits, disable them.
https://help.steampowered.com/en/faqs/view/1F39-DCB4-FF28-5748
The above shows an extensive list of potential programs that could interfere with Steam.