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While I've had pretty good luck swapping out hardware on the same install of Windows. There's always a chance it doesn't go well.
If it were me, as Snakub and Muppet advised, I would do a fresh install of the entire OS. Windows doesn't handle platform changes well.
Stick it in your machine and set the BIOS to boot from the usb
Follow the prompts
Most likely your key won't be re-usable unless it's a retail key so you're going to have to buy an OEM one somewhere.
I would also save any important files prior to doing this.
If you want to wait for your friend, you can prepare the usb stick in advance